There is no Discover credit card daily limit. The amount you can withdraw will depend on your own cash advance limit.
Cash advances are expensive, though. I suggest you avoid them as much as possible, because any short term benefit they might offer is outweighed by their cost.
Discover’s cash advance APR is 29.99% Variable, and it also charges a fee for all of their cards: Either $10 or 5% of the amount of each cash advance, whichever is greater. You could also be charged with ATM fees, when you use one that isn’t affiliated with Discover.
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